Google doesn't see anything just because it uses web technology. For instance, the payroll system I use is a web app, but Google doesn't see my company's payroll data. What Google sees is a marketing blurb about the payroll system.
Google sees everything that is public and everything that uses their ad network, including data from apps that don't use the web at all.
Google sees everything that is public and everything that uses their ad network, including data from apps that don't use the web at all.